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SyncoZymes

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Ene reductase (ERED) Sawirka sifaysan
  • Ene reductase (ERED)

Ene reductase (ERED)

Sharaxaad Gaaban:

Ku saabsan ene reductase

ES-EREDs: Waxay ka tirsan yihiin qoyska enzymes jaalaha ah ee hore kuwaas oo si xushmad leh u yareeya C = C ee α, β - xeryahooda aan la daboolin oo leh kooxo elektaroonig ah.Waxaa si weyn loogu isticmaalaa daraasadda soosaarayaasha amino acids, walxaha bioactive, dhexdhexaadiyeyaasha dawooyinka, dhir udgoon iyo blocks chiral.

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Faahfaahinta Alaabta

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Ku saabsan ene reductase:

ES-EREDs waxay kiciyaan noocyo kala duwan oo substrate ah sababtoo ah noocyada kala duwan ee substrates.Guud ahaan, C = C ee α, β-unsaturated xeryahooda oo leh kooxaha nuugista elektarooniga ah (oo ay ku jiraan ketone aldehyde, kooxaha nitro, acids carboxylic, esters, anhydride, lactones, imines, iwm) ayaa si fudud loo dhimay ES-EREDs, laakiin bond double unactivated ma.

Waxaa jira 46 nooc oo ah alaabada enzyme ERED (Lambarka ES-ERED-101~ES-ERED-146) oo ay soo saartay SyncoZymes.

Farsamaynta catalytic:

Ene reductase EED1

Macluumaadka Alaabta:

Ene reductase EED2
Enzymes Koodhka badeecada Tilmaamid
Budada Enzyme ES-ERED-101~ ES-ERED-146 46 Ene Reductases, 50 mg 46 walxood * 50mg / shayga, ama tiro kale
Qalabka Baaritaanka (SynKit) ES-ERED-4600 46 Ene Reductases, 50 mg 46 walxood * 50mg / shayga, ama tiro kale

Faa'iidooyinka:

★ gaar ahaan substrate-ka sare.
★ Xulasho xoog leh oo chiral ah.
★ beddelaad sare.
★ Alaabooyin ka yar
★ Xaalado falcelin fudud.
★ deegaan ahaan.
★ Badbaadada sare.

Tilmaamaha isticmaalka:

Caadiyan, habka falcelinta waa in lagu daraa substrate, xal-celin (pH falcelinta ugu fiican), coenzymes (NAD (H) ama NADP (H)), nidaamka dib u soo kabashada koenzyme (tusaale gulukoos iyo gulukoos dehydrogenase) iyo ES-ERED.
➢ Dhammaan ES-ERED-yada waxa lagu tijaabin karaa siday u kala horreeyaan habka falcelinta ee kore ama Qalabka Baadhista ERED (SynKit ERED).
➢ Dhammaan noocyada ES-ERED ee u dhigma xaaladaha kala duwan ee falcelinta ugu wanaagsan waa in si gaar ah loo darso.
➢ Substrate-ka-fiirsashada sare ama badeecada leh ayaa laga yaabaa inay hakiso hawsha ES-ERED.Si kastaba ha ahaatee, xannibaadda waxaa lagu nafisi karaa marka lagu daro qayb ka mid ah substrate.

Tusaalooyinka Codsiga:

Tusaale 1 (α, β-unsaturated aldehyde ama ketones)(1):

Ene reductase EED3

Tusaalaha 2 (α, β-karboksylic acids iyo kuwa ka soo jeeda)(2):

Ene reductase EED4

Kaydinta:

Ka dhig 2 sano ka hooseeya -20 ℃.

Fiiro gaar ah:

Weligaa ha la xiriirin xaaladaha ba'an sida: heerkulka sare, pH sare/hoose iyo dareeraha organic-fiirsashada sare leh.

Tixraacyo:

1. Lucídio C, Fardelone J, Augusto R, iyo tal.J.Mol.Catal.B:Enzym., 2004, 29: 41-45.
2. Stueckler C, Hall M, Ehammer H, iyo talaal..Org.Lett, 2007, 9 (26): 5409-5411.

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